Hyper-Rayleigh scattering

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Hyper-Rayleigh scattering spectrum of liquid nitromethane.

The vertical vertical (VV), horizontal vertical (HV), and vertical horizontal (VH) hyper-Rayleigh scattering (HRS) spectra were measured for liquid CH3NO2 at T= 300 K. The main HRS spectral component has a width upsilon1=1.28 +/- 0.04 cm(-1), which gives an orientation relaxation time pi=4.1 +/- 0.1 ps in good agreement with other experiments. However, the VH spectrum also contains a previously...

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Spectral measurements of hyper-Rayleigh light scattering

An apparatus is described for the measurement of second-order nonlinear optical properties via hyper-Rayleigh scattering with 1 cm spectral resolution of the scattered light. The setup allows a complete investigation of the polarization dependence of the second-harmonic scattered light. The combination of good spectral resolution, polarization analysis, and high sensitivity allows the determina...

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Hyper-Rayleigh scattering in centrosymmetric systems.

Hyper-Rayleigh scattering (HRS) is an incoherent mechanism for optical second harmonic generation. The frequency-doubled light that emerges from this mechanism is not emitted in a laser-like manner, in the forward direction; it is scattered in all directions. The underlying theory for this effect involves terms that are quadratic in the incident field and involves an even-order optical suscepti...

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Accurate hyper-Rayleigh scattering polarization measurements.

Apparatus and methods are described for measurement of the polarization dependence of hyper-Rayleigh scattering near 90° scattering angle with 0.1% accuracy for all four configurations where the incident and scattered light is linear polarized either parallel or perpendicular to the scattering plane. Measurements are made with large collection aperture and extrapolated to zero collection numeri...

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Hyper-Rayleigh scattering from correlated molecules.

The polarization dependence of hyper-Rayleigh scattering has been calculated for spherical domains of orientation correlated molecules. Distributions with radial or azimuthal mean polar orientation of the molecules are found that give results consistent with experimental observations, and expressions for the polarization ratios in terms of the product of correlation strength and correlated doma...

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ژورنال

عنوان ژورنال: Nature Photonics

سال: 2019

ISSN: 1749-4885,1749-4893

DOI: 10.1038/s41566-019-0410-x